This work is devoted to the physico-chemical study of cadmium and lead interaction with diatom–water interfaces for two marine planktonic (Thalassiosira weissflogii = TW, Skeletonema costatum = SC) and two freshwater periphytic species (Achnanthidium minutissimum = AMIN, Navicula minima = NMIN) by combining adsorption measurements with surface complexation modeling. Reversible adsorption experiments were performed at 20 °C after 3 h of exposure as a function of pH, metal concentration in solution, and ionic strength. While the shape of pH-dependent adsorption edge is similar among all four diatom species, the constant-pH adsorption isotherm and maximal binding capacities differ. These observations allowed us to construct a surface complexation model for cadmium and lead binding by diatom surfaces that postulates the constant capacitance of the electric double layer and considers Cd and Pb complexation with mainly carboxylic and, partially, silanol groups. Parameters of this model are in agreement with previous acid–base titration results and allow quantitative reproduction of all adsorption experiments. 相似文献
Argillaceous rocks cover about one thirds of the earth's surface. The major engineering problems encountered with weak- to medium-strength argillaceous rocks could be slaking, erosion, slope stability, settlement, and reduction in strength. One of the key properties for classifying and determining the behavior of such rocks is the slake durability. The concept of slake durability index (SDI) has been the subject of numerous researches in which a number of factors affecting the numerical value of SDI were investigated. In this regard, this paper approaches the matter by evaluating the effects of overall shape and surface roughness of the testing material on the outcome of slake durability indices.
For the purpose, different types of rocks (marl, clayey limestone, tuff, sandstone, weathered granite) were broken into chunks and were intentionally shaped as angular, subangular, and rounded and tested for slake durability. Before testing the aggregate pieces of each rock type, their surface roughness was determined by using the fractal dimension. Despite the variation of final values of SDI test results (values of Id), the rounded aggregate groups plot relatively in a narrow range, but a greater scatter was obtained for the angular and subangular aggregate groups. The best results can be obtained when using the well rounded samples having the lowest fractal values. An attempt was made to analytically link the surface roughness with the Id parameter and an empirical relationship was proposed. A chart for various fractal values of surface roughness to use as a guide for slake durability tests is also proposed. The method proposed herein becomes efficient when well rounded aggregates are not available. In such condition, the approximate fractal value for the surface roughness profile of the testing aggregates could be obtained from the proposed chart and be plugged into the empirical relation to obtain the corrected Id value. The results presented herein represent the particular rock types used in this study and care should be taken when applying these methods to different type of rocks. 相似文献
Porous fence is a kind of artificial windbreak that has many practical applications. The threshold wind velocities at different distances downwind from porous fences were measured and the corresponding characteristics of particle movement observed to assess their shelter effect. It is found that the fence’s porosity is the key factor that determines the resulting shelter effect. The area near a fence can be typically classified into five regions, each with a different mode of particle movement. Dense fences, and especially solid fences, favor the accumulation of sand upwind of the fences. Fences with porosities of 0.3–0.4 produce the maximum threshold wind velocity; those with porosities of 0.3–0.6 (depending on the fence height) provide the maximum effective shelter distance. It is confirmed that the fence porosities of 0.3–0.4 that have been proposed for practical application in previous research are the most effective for abating wind erosion. 相似文献
For more than hundred years it has been debated whether blockfields in mountain summit areas can be used to delimit the vertical extent of Pleistocene ice sheets. In this study the relationship between blockfields, developed in quartzites and sandstones on the Varanger Peninsula, northern Norway, and glacially derived features have been evaluated. Erratics and circular ablation moraines are superimposed on the blockfields and lateral meltwater channels are eroded into them. Glacial striations and other signs of glacial sculpturing are restricted to low-lying areas with channelled ice flow. Relative ages of the blockfields and the features in them are inferred, and the first measurements of in-situ produced cosmogenic nuclides from the Varanger Peninsula are reported. We conclude that the blockfields have survived underneath at least one thick, cold-based ice sheet. Thus, these blockfields cannot be used as indicators of ice-free conditions as previously suggested for southern Norway. Our results have implications for the potential for land surface preservation beneath ice sheets and for glacial reconstructions in northern Fennoscandia. 相似文献
This paper updates a life-cycle net energy analysis and carbon dioxide emissions analysis of three Midwestern utility-scale
wind systems. Both the Energy Payback Ratio (EPR) and CO2 analysis results provide useful data for policy discussions regarding an efficient and low-carbon energy mix. The EPR is
the amount of electrical energy produced for the lifetime of the power plant divided by the total amount of energy required
to procure and transport the materials, build, operate, and decommission the power plants. The CO2 analysis for each power plant was calculated from the life-cycle energy input data.
A previous study also analyzed coal and nuclear fission power plants. At the time of that study, two of the three wind systems
had less than a full year of generation data to project the life-cycle energy production. This study updates the analysis
of three wind systems with an additional four to eight years of operating data.
The EPR for the utility-scale wind systems ranges from a low of 11 for a two-turbine system in Wisconsin to 28 for a 143-turbine
system in southwestern Minnesota. The EPR is 11 for coal, 25 for fission with gas centrifuge enriched uranium and 7 for gaseous
diffusion enriched uranium. The normalized CO2 emissions, in tonnes of CO2 per GWeh, ranges from 14 to 33 for the wind systems, 974 for coal, and 10 and 34 for nuclear fission using gas centrifuge and gaseous
diffusion enriched uranium, respectively. 相似文献